Apologies for the delayed reply. In F# 1.1.12 the concrete type for BigInt lives at Microsoft.FSharp.Math.Types.BigInt. If you open Microsoft.FSharp.Math.Types you should get a lot further, or at least make a type alias
using bigint = Microsoft.FSharp.Math.Types.BigInt
In F# 1.1.13 the concrete type definition will actually be moving to Microsoft.FSharp.Math as part of a general library cleanup and rationalization. So you went looking in the right place, it's just not there yet :-) But you can always find out the concrete canonical type name using the documentation at http://research.microsoft.com/fsharp/manual/fslib/Microsoft.FSharp.type_bigint.html etc.
Don